Multifunctional SGCG/CuO₂ composite hydrogel for integrated wastewater remediation: Copper ions removal, phenolic...

Hydrogel-based materials have emerged as promising candidates for wastewater remediation due to their remarkable adsorption capacity, recyclability, and environmental compatibility. In this study, we developed a multifunctional sodium alginate-glutaraldehyde-chitosan-gelatin (SGCG) composite hydrogel with enhanced mechanical properties and abundant functional groups (-COOH, -NH₂) for efficient Cu²⁺ sequestration. Investigation of adsorption parameters revealed optimal conditions and underlying mechanisms for heavy metal removal. Subsequent in situ reaction of the Cu²⁺-loaded hydrogel (SGCG/Cu²⁺) with H₂O₂ yielded a nanozyme composite (SGCG/CuO₂) with dual enzyme-mimetic activities: laccase-like activity for phenolic pollutant degradation and peroxidase-like activity for antibacterial applications. The SGCG/CuO₂ hydrogel exhibited exceptional performance in removing phenolic contaminants and inactivating pathogenic bacteria (Staphylococcus aureus (S. aureus) and Escherichia coli (E. coli)), owing to its robust catalytic properties. This work presents an innovative multifunctional hydrogel system that integrates heavy metal adsorption, catalytic organic degradation, and antimicrobial activity into a single platform, offering a sustainable and efficient solution for complex wastewater remediation.