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Updated: Sep 11, 2025

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Published on: May 7, 2019
One-pot synthesis of atomically precise chiral PtAg4 nanoclusters
Yujie Zhang1, Hongli Jia2, Bingzheng Yan1
1College of Energy Materials and Chemistry, Inner Mongolia University, Hohhot 010021, China. shen@imu.edu.cn.
Abstract:
We report the synthesis and structural characterization of [PtAg4Cl(BDPP)4H]2+, a novel bimetallic complex featuring an intrinsically chiral architecture. The heterometallic Pt-Ag core exhibits distinctive optical properties, while the chiral BDPP (BDPP is 2,4-bis(diphenylphosphino)pentane) ligand not only induces structural asymmetry but also fine-tunes the electronic and steric characteristics of the complex.
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