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Updated: Sep 11, 2025

Measurement of Ultrafast Vibrational Coherences in Polyatomic Radical Cations with Strong-Field Adiabatic Ionization
Published on: August 6, 2018
Measurement of the Differential Static Scalar Polarizability of the ^{88}Sr^{+} Clock Transition
T Lindvall1, K J Hanhijärvi1, T Fordell1
1VTT Technical Research Centre of Finland Ltd, National Metrology Institute VTT MIKES, P.O. Box 1000, FI-02044 VTT, Finland.
Abstract:
We report on a precision measurement of the differential static scalar polarizability Δα_{0} of the ^{2}S_{1/2}→^{2}D_{5/2} optical clock transition in the ^{88}Sr^{+} ion. The polarizability was determined from the "magic" ion-trap drive frequency where the micromotion-induced second-order Doppler and quadratic Stark shifts cancel, using a single clock in an interleaved scheme by switching between minimized and large micromotion. By measuring at different Mathieu q_{z} parameters, Δα_{0} can be obtained without prior knowledge of the angle between the rf electric field and the trap axis, which would otherwise dominate the systematic uncertainty. For validation, measurements were carried out at different micromotion levels and by displacing the ion in opposite directions. The results show excellent consistency and our value, Δα_{0}=-4.8314(20)×10^{-40} Jm^{2}/V^{2}=-29.303(12) au, reduces the uncertainty by a factor of 3.5 compared to a previous measurement, while showing a discrepancy of 5σ. Our measurement reduces the polarizability-related uncertainty of the ^{88}Sr^{+} clock to 2.2×10^{-19} for a blackbody radiation temperature of 295 K-a significant step towards total uncertainties <1×10^{-18}. Using existing polarizability transfer schemes, the result can reduce the uncertainty also for other ion species.
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