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Updated: Sep 11, 2025

Non-equilibrium Microwave Plasma for Efficient High Temperature Chemistry
Published on: August 1, 2017
Definition of electron temperature of nonequilibrium plasma based on Tsallis and Rényi entropy maximization
Koji Kikuchi1, Hiroshi Akatsuka2
1Institute of Science Tokyo, Graduate Major in Nuclear Engineering, Department of Electrical and Electronic Engineering, 2-12-1-N1-10, O-Okayama, Meguro-ku, Tokyo 152-8550, Japan.
Abstract:
Nonequilibrium plasma has attracted significant attention owing to its excellent physical properties, which are highly valued by the industrial community. However, determining the electron temperature in nonequilibrium plasmas proves challenging unless the energy distribution function is approximated as an ideal Maxwell-Boltzmann distribution, where the slope of the Boltzmann plot is directly related to temperature based on traditional Boltzmann-Gibbs statistics. To overcome this problem, Tsallis and Rényi entropies are applied to nonequilibrium systems using nonextensive Tsallis and extensive Rényi statistics, respectively. Here, the temperature is determined through a power-law distribution derived from the entropy maximization principle, which accounts for the influence of previously neglected high-energy electrons. However, because the resulting distribution function requires a self-consistent function that cannot be solved analytically, a self-consistent iterative scheme is proposed to calculate the temperature. Consequently, the electron temperature is uniquely determined in nonequilibrium plasmas, satisfying the entropy maximization principle. This study may open additional avenues for understanding plasma properties using an additional parameter q expanding the meaning of temperature T.
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