Acid-Modified Biochar Derived from Agricultural Waste for Efficiently Capturing Low-Concentration Nitrous Oxide...

Low-concentration N₂O (≤5%) emissions from agricultural fields and waste treatment facilities in China reach 7.333 × 10⁵ t annually, making them a significant but inadequately controlled contributor to global warming. Agricultural wastes were selected as precursors to prepare biochar, including pecan shell (SH), poplar sawdust (JM), wheat straw (XM), and corn straw (YM), which were subsequently acid-modified with 0.1 mol L^-1 HCl. The objectives were (i) to quantify the enhancement in N₂O capture achievable by acid treatment, (ii) to elucidate the underlying chemisorption mechanism, and (iii) to identify the most efficient feedstock for practical deployment. Acid modification increased the oxygen content, specific surface area, and the number of hydroxyl and carboxyl groups on the biochar surface. Both modified and unmodified biochar followed the pseudo-second-order kinetic model (R² ≥ 0.960), indicating chemisorption-dominated processes. The adsorption performance ranked as XM > JM > SH > YM, with XM exhibiting the highest adsorption capacity (26.000 mol/kg unmodified, 43.088 mol/kg modified, 65.72% increase). The Langmuir model provided a better fit for N₂O adsorption, suggesting dynamic multilayer heterogeneous adsorption. The findings demonstrate that acid-modified biochar derived from agricultural waste is a scalable, economical, and environmentally friendly adsorbent for mitigating low-concentration N₂O emissions.