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Updated: Sep 9, 2025
Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries Using Synchrotron Radiation Techniques
Published on: November 11, 2013
Designing a pseudocapacitive binary Zn/Mn perovskite fluoride anode with a conversion/alloying/insertion hybrid
1Key Laboratory of Environmentally Friendly Chemistry and Applications of Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan, Hunan 411105, P.R. China. drm8122@xtu.edu.cn.
Abstract:
Na-ion capacitors (NICs) and Na-based dual ion batteries (Na-DIBs) have received intensive attention due to their high energy density, high power density, and long cycle life and the low cost of sodium. Hence, a novel perovskite KZMF(3-1)@rGO nanocrystal used as the sodium-storage anode is coupled with an activated carbon (AC) cathode and a graphite (KS6) cathode to construct NICs and Na-DIBs, respectively. The KZMF(3-1)@rGO electrode with a superconducting carbon black (SP) conductive agent and 0.85 M NaPF6/EC : DEC : EMC(1 : 1 : 1)/5% FEC electrolyte delivers high capacity (114 mAh g-1/0.05 A g-1) and ultralong cycling performance (75%/500/0.3 A g-1). The constructed KZMF(3-1)@rGO//AC NICs and KZMF(3-1)@rGO//KS6 Na-DIBs even demonstrated excellent energy/power densities (73.2-33.4 Wh kg-1/0.54-17.2 kW kg-1, 200.2-22.9 Wh kg-1/0.98-23.5 kW kg-1) and cycle life (68%/1000/5 A g-1, 61%/1000/5 A g-1). Furthermore, this paper verifies the hybrid conversion/alloying/insertion reaction mechanism of the KZMF(3-1)@rGO anode by electrochemical analysis and ex situ characterization, which provides new insights and ideas for the future development of new anode materials.
