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Fabricating Superhydrophobic Polymeric Materials for Biomedical Applications
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A Supraparticle-Based Approach to Robust Biomimetic Superhydrophobic Coatings.

Umair Sultan1, Teresa Walter1, Christian Wachter1

  • 1Institute of Interfaces and Particle Technology, Friedrich-Alexander-Universität Erlangen-Nürnberg, Cauerstrasse 4, 91058, Erlangen, Germany.

Small (Weinheim an Der Bergstrasse, Germany)
|September 5, 2025
PubMed
Summary

This study introduces a fluorine-free method to create durable superhydrophobic coatings using supraparticles. This scalable technique mimics the lotus leaf

Keywords:
biomimeticrepellent coatingsrobustnesssuperhydrophobicsupraparticles

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Area of Science:

  • Materials Science
  • Surface Chemistry
  • Nanotechnology

Background:

  • Repellent surfaces resist biofouling, ice, and corrosion by minimizing water adhesion.
  • Lotus leaf-inspired hierarchical micro/nanostructuring is key to superhydrophobicity.
  • Existing methods often use harmful fluorinated compounds or lack durability.

Purpose of the Study:

  • Develop a fluorine-free, scalable, and robust method for superhydrophobic coatings.
  • Utilize supraparticles as building blocks for hierarchical surface roughness.
  • Mimic the lotus leaf's water-repellent properties.

Main Methods:

  • Fabrication of supraparticles via spray drying.
  • Introduction of hydrophobicity using alkyl-silanes.
  • Spray coating of supraparticles onto a polymeric primer layer.

Main Results:

  • Demonstrated hierarchical surface roughness mimicking the lotus leaf.
  • Quantified superhydrophobic performance using contact angles and roll-off angles.
  • Showcased enhanced robustness through binder addition and primer selection.

Conclusions:

  • The supraparticle approach offers a simple, scalable, and versatile strategy.
  • Achieved durable superhydrophobic coatings without problematic fluorinated compounds.
  • This method enables robust, lotus leaf-inspired surfaces for various applications.