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Related Concept Videos

Isochoric and Isobaric Processes01:21

Isochoric and Isobaric Processes

4.2K
A thermodynamic process that occurs at constant volume is called an isochoric process. According to the first law of thermodynamics, heat supplied or removed from the system is partially utilized to perform work and change the internal energy of the system. However, in an isochoric process, the volume remains constant. Hence, the work done by the system is zero. Therefore, the exchange of heat changes the internal energy of the system only. 
Suppose 1000 g of water is heated from 40...
4.2K
Isothermal Processes01:21

Isothermal Processes

4.9K
A thermodynamic process that occurs at constant temperature is called an isothermal process. Heat slowly flows into the system or out of the system to maintain thermal equilibrium. Processes involving phase changes like water evaporation into steam or freezing water into ice at a constant temperature are examples of Isothermal Processes.
An ideal gas can also undergo isothermal expansion or compression.
For example, consider 1 mole of an ideal gas inside an isolated cylinder at initial volume V...
4.9K
pV-Diagrams01:18

pV-Diagrams

6.1K
The pV diagram, which is a graph of pressure versus volume of the gas under study, is helpful in describing certain aspects of the substance. When the substance behaves like an ideal gas, the ideal gas equation describes the relationship between its pressure and volume. On a pV diagram, it is common to plot an isotherm, which is a curve showing p as a function of V with the number of molecules and the temperature fixed. Then, for an ideal gas, the product of the pressure of the gas and its...
6.1K
Thermodynamic Potentials01:26

Thermodynamic Potentials

1.5K
Thermodynamic potentials are state functions that are extremely useful in analyzing a thermodynamic system. They have dimensions of energy. The four important thermodynamic potentials are internal energy, enthalpy, Helmholtz free energy, and Gibbs free energy. These thermodynamic potentials can be expressed using two of the following variables: pressure, volume, temperature, and entropy. These two variables are expressed as the rate of change of the thermodynamic potential with respect to other...
1.5K
Efficiency of The Carnot Cycle01:16

Efficiency of The Carnot Cycle

3.6K
The hypothetical Carnot cycle consists of an ideal gas subjected to two isothermal and two adiabatic processes. Since the internal energy of an ideal gas depends only on its temperature, which is the same before and after the completion of the Carnot cycle, there is no change in its internal energy. Hence, using the first law of thermodynamics, the total heat exchanged by the ideal gas equals the total work done. Thus, we can quantify the efficiency of the Carnot cycle via the heat exchanged...
3.6K
The Carnot Cycle and the Second Law of Thermodynamics01:20

The Carnot Cycle and the Second Law of Thermodynamics

3.7K
The Carnot engine works between two heat reservoirs of fixed temperatures. The Carnot cycle begs the following question: Is it possible to devise a heat engine that is more efficient than a Carnot engine between two fixed temperatures? The answer lies in designing a Carnot refrigerator.
Since the individual steps in a Carnot cycle can be reversed, the entire cycle is, thus, reversible. If a Carnot cycle is reversed, it becomes a Carnot refrigerator. It extracts heat Qc from a cold reservoir at...
3.7K

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Correction to "Analytic Correlation for the Thermodynamic Properties of Water at Low Temperatures (200-300 K) and High Pressures (0.1-400 MPa)".

The journal of physical chemistry. B·2025
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Stability Analysis of a Multicomponent Vapor-Gas Bubble in Contact with a Liquid-Gas Solution.

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Predictive Thermodynamics for Isochoric (Constant-Volume) Cryopreservation Systems.

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Analytic Correlation for the Thermodynamic Properties of Water at Low Temperatures (200-300 K) and High Pressures (0.1-400 MPa).

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Related Experiment Video

Updated: Jan 17, 2026

Measuring the Densities of Aqueous Glasses at Cryogenic Temperatures
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Measuring the Densities of Aqueous Glasses at Cryogenic Temperatures

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Correction to "Predictive Thermodynamics for Isochoric (Constant-Volume) Cryopreservation Systems"

Julia H Grenke, Janet A W Elliott

    The Journal of Physical Chemistry. B
    |September 22, 2025
    PubMed
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    No abstract available in PubMed .

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