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Updated: Jan 16, 2026

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
Published on: June 21, 2017
Aminoquinoline-Directed Electrochemical Cobalt-Catalyzed C(sp²)-H Alkoxylation
Li-Bo Li1, Zhi-Xiong Ou1, Bu-Hong Zhang1
1Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. China.
Abstract:
Electrochemically, earth-abundant cobalt(II)-catalyzed C(sp2)-H alkoxylation of ferrocenyl and arenyl amides with 8-aminoquinoline directing groups was developed under mild, oxidant-free conditions. This protocol afforded a broad range of alkoxylated products in moderate to high yields, employing readily available alcohols as both alkoxy sources and green solvents. Notably, this method enabled efficient C-O bond formation via sustainable electrolysis and offered a practical route to alkylated organic compounds.
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