Structure-Property-Performance Relationships in Thermoplastic Polyurethane: Influence of Infill Density and Surface...

This study investigates the structure-property-performance (SPP) relationships of two thermoplastic polyurethanes (TPUs), FILAFLEX FOAMY 70A and SMARTFIL^® FLEX 98A, manufactured by fused filament fabrication (FFF). Disc specimens were produced with varying gyroid infill densities (10-100%) and Archimedean surface textures, and their tribological and surface characteristics were analyzed through Ball-on-Disc tests, profilometry, and optical microscopy. SMARTFIL^® FLEX 98A exhibited a sharp reduction in the coefficient of friction (μ) with increasing infill, from 1.174 at 10% to 0.371 at 100%, linked to improved structural stability at higher densities. In contrast, FILAFLEX FOAMY 70A maintained a stable but generally higher coefficient of friction (0.585-0.729) across densities, reflecting its foamed microstructure and bulk yielding behavior. Surface analysis revealed significantly higher roughness in SMARTFIL^® FLEX 98A, while FILAFLEX FOAMY 70A showed consistent roughness across infill levels. Both TPUs resisted inducing abrasive wear on the steel counterpart, but their stress-accommodation mechanisms diverged. These findings highlight distinct application profiles: SMARTFIL^® FLEX 98A for energy-absorbing, deformable components, and FILAFLEX FOAMY 70A for applications requiring stable surface finish and low adhesive wear. The results advance the design of functionally graded TPU materials through the controlled tuning of infill and surface features.