A Facile Fluorescent Visualization Method Based on Copper Clusters for Formaldehyde Detection
Jie Zou1, Qing Chen1, Guimin Mu1
1Key Laboratory of Pollution Control Chemistry and Environmental Functional Materials for Qinghai-Tibet Plateau of the National Ethnic Affairs Commission, School of Chemistry and Environment, Southwest Minzu University, Chengdu 610041, China.
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Establishing a simple and effective method for the visual detection of formaldehyde plays an important role in environmental emergency monitoring. In this work, L-cysteine-stabilized copper clusters were synthesized via a green, mild, and facile one-step preparation method. Through the optimization of reaction conditions, including reactant concentration and pH, the clusters exhibited stable red fluorescence. Upon exposure to formaldehyde, the fluorescence intensity of copper clusters gradually quenched with increasing formaldehyde concentration, enabling the development of a visual detection method that was successfully applied to analyze formaldehyde samples in air. Furthermore, by immobilizing the copper clusters into hydrogels, the visual detection performance and portability of the material were significantly enhanced. This method offers the advantages of simple preparation and rapid and accurate determination, demonstrating potential for semi-quantitative field detection of formaldehyde in emergency scenarios.
