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¹H NMR: Long-Range Coupling01:27

¹H NMR: Long-Range Coupling

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The coupling interactions of nuclei across four or more bonds are usually weak, with J values less than 1 Hz. While these are usually not observed in spectra, the presence of multiple bonds along the coupling pathway can result in observable long-range coupling.
In alkenes, spin information is communicated via σ–π overlap, as seen in allylic (four-bond) and homoallylic (five-bond) couplings. These coupling interactions are stronger when the σ bond is parallel to the alkene...
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Fabrication And Characterization Of Photonic Crystal Slow Light Waveguides And Cavities
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Long-range optical coupling with epsilon-near-zero materials.

Danqing Wang1,2,3,4, Zheyu Lu5,6,7, Sorren Warkander8

  • 1College of Future Information Technology, Shanghai Engineering Research Centre of Ultra-precision Optical Manufacturing, Fudan University, Shanghai, China. danqingwang@fudan.edu.cn.

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|October 16, 2025
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Summary
This summary is machine-generated.

Researchers demonstrate long-range optical interactions using epsilon-near-zero materials, analogous to quantum tunneling. Intense electromagnetic fields show anti-correlated oscillations in thin films, enabling new photonic applications.

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Area of Science:

  • Photonics
  • Quantum Optics
  • Materials Science

Background:

  • Quantum tunneling enables electron transport via wavefunction interference.
  • Evancescent coupling typically limits optical interactions in thin films.

Purpose of the Study:

  • To demonstrate an optical analogy to long-range resonant quantum tunneling.
  • To explore phase-modulated optical interactions beyond evanescent coupling.
  • To investigate applications in optical communication and photonic circuits.

Main Methods:

  • Utilizing epsilon-near-zero (ENZ) materials for optical interactions.
  • Confining intense electromagnetic fields within ENZ thin films.
  • Probing field intensities using second harmonic generation in indium tin oxide multilayers.

Main Results:

  • Achieved long-range optical interactions between oxide layers up to hundreds of microns.
  • Observed anti-correlated intensity oscillations of confined electromagnetic fields.
  • Demonstrated subwavelength mode footprint with long-range radiative coupling.

Conclusions:

  • ENZ materials enable novel long-range optical interactions analogous to quantum tunneling.
  • The observed phenomena offer potential for advanced optical communication and large-scale photonic systems.
  • This work paves the way for hybrid quantum photonic systems.