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Extraction of Lignin with High β-O-4 Content by Mild Ethanol Extraction and Its Effect on the Depolymerization Yield
Published on: January 7, 2019
Reductive-Oxidative Tandem Catalysis for Lignin Depolymerization to Benzoquinones and Benzaldehydes
Jonas Mortier1, Tibo De Saegher2, Christian V Stevens1
1Department of Green Chemistry and Technology, Faculty of Bioscience Engineering, Ghent University, Coupure Links 653, 9000, Ghent, Belgium.
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This study investigates a tandem Pd-catalyzed reductive depolymerization of lignin and subsequent Co(salen)-catalyzed oxidative cleavage to obtain benzoquinones and benzaldehydes. The reductive depolymerization will result in lignin macromolecules with heavily increased phenolic OH content, which are then selectively cleaved by the Co(salen) catalyst to yield benzoquinones and benzaldehydes. Compared to lignin samples that do not undergo reductive depolymerization first, benzoquinone yields are substantially increased.
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