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An Emerging Era of Multi-Metallic High-Entropy Photon-Stimulated Materials
Nallin Sharma1, Chandan Srivastava1
1Department of materials engineering, Indian Institute of Sciences, CV Raman Road, Bengaluru, 560012, India.
Chemistry (Weinheim an Der Bergstrasse, Germany)
|October 28, 2025
Summary
High Entropy Materials (HEMs) exhibit unique optical properties and tunable bandgaps. This review focuses on HEM nanostructures for advanced photo-stimulated applications like photothermal and photocatalysis.
Area of Science:
- Materials Science
- Nanotechnology
- Optoelectronics
Background:
- High Entropy Materials (HEMs), alloys with five or more principal metals, show exceptional mechanical and catalytic properties.
- Recent research highlights HEMs' tunable optical properties, spanning visible to infrared wavelengths.
- Existing reviews focus on HEMs' mechanical and electrocatalytic aspects, leaving photo-stimulated properties under-explored.
Purpose of the Study:
- To review novel High Entropy (HE) nanostructures and their emerging roles in photo-stimulated applications.
- To consolidate research on HEMs as photoabsorbers, photothermal agents, photodetectors, photoemitters, photocatalysts, and photochromic materials.
- To address the gap in literature concerning the photo-stimulated properties of HEMs.
Main Methods:
- Literature review of recent advancements in High Entropy Materials (HEMs).
- Focus on nanostructured HEMs, including HE-MXene, HE-layered hydroxides, and HE-alloy nanoparticles.
- Analysis of HEMs' applications in photothermal and photocatalysis.
Main Results:
- HEMs offer significant advantages in optical properties, including bandgap tunability.
- Various nanostructured HEMs are being developed for enhanced performance in photo-stimulated processes.
- HEMs show promise for applications in photoabsorbers, photothermal conversion, photocatalysis, and photochromic devices.
Conclusions:
- HEMs represent a promising class of materials for advanced photo-stimulated applications.
- The unique properties of HE nanostructures are crucial for overcoming current efficiency limitations.
- Further research into HEMs' photo-stimulated functionalities is warranted.

