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Updated: Aug 9, 2026

Amide Coupling Reaction for the Synthesis of Bispyridine-based Ligands and Their Complexation to Platinum as Dinuclear Anticancer Agents
Published on: May 28, 2014
Practical synthesis of ferrocenyldiarylstibines and bismuthines
David Rezazgui1, Jiří Schulz1, Petr Štěpnička1
1Department of Inorganic Chemistry, Faculty of Science, Charles University, Hlavova 2030, 128 00 Prague, Czech Republic. stepnicz@natur.cuni.cz.
Abstract:
The reaction of in situ-generated lithioferrocene with pnictines EAr3 (E = Sb and Bi, Ar = aryl) is presented as a reliable, robust, and practical approach for synthesising ferrocenyldiarylstibines and bismuthines. In addition to simple derivatives FcEAr2 (Fc = ferrocenyl), the method enables the preparation of functional derivatives, thereby opening access to P,Sb and P,Bi-hybrids.
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