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Properties of Organometallic Compounds

Properties of Organometallic Compounds

Organometallic compounds are compounds that contain a carbon–metal bond. Carbon belongs to an organyl group like alkyl, aryl, allyl, or benzyl groups. The metal can be from Group I or Group II of the periodic table, a transition metal, or a semimetal.

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Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks MOFs

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Published on: January 17, 2020

Metal-organic framework (Pd-DTPA-MOF)-based materials as heterogeneous catalysts for C-S cross-coupling reactions.

Anjan Kumar¹, Rana Said², Munthar Kadhim Abosaoda^3,4

¹Department of electronics and communication engineering, GLA University, Mathura, 281406, India. k.anjan20102010@gmail.com.

Scientific Reports

|November 1, 2025

Summary

A novel palladium-DTPA metal-organic framework (MOF) shows high efficiency in C-S cross-coupling reactions. This reusable nanocatalyst offers high yields and an eco-friendly synthesis process.

Keywords:

Catalyst Coupling DTPA MOF Pd

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HKUST-1 as a Heterogeneous Catalyst for the Synthesis of Vanillin

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Published on: July 23, 2016

Area of Science:

Materials Science
Catalysis
Nanotechnology

Background:

Metal-organic frameworks (MOFs) are advanced porous materials with diverse applications.
Palladium-catalyzed cross-coupling reactions are crucial in organic synthesis.
Developing efficient and reusable catalysts is essential for sustainable chemistry.

Purpose of the Study:

To synthesize and characterize a novel palladium-DTPA-MOF.
To evaluate the catalytic performance of the Pd-DTPA-MOF in C-S cross-coupling reactions.
To assess the recyclability and stability of the synthesized nanocatalyst.

Main Methods:

Hydrothermal synthesis using palladium acetate and DTPA.
Characterization via FT-IR, TGA, XRD, EDS, BET, SEM, and ICP.
Catalytic testing in C-S cross-coupling reactions under mild conditions.

Main Results:

Successful synthesis of a nanostructured Pd-DTPA-MOF.
Demonstrated high efficiency and yield in C-S cross-coupling reactions.
Catalyst recovery via centrifugation and reuse for up to four cycles with minimal activity loss.

Conclusions:

The developed Pd-DTPA-MOF is an efficient and recyclable nanocatalyst for C-S cross-coupling.
The synthesis is simple and the material exhibits environmentally friendly characteristics.
This MOF presents a promising alternative for sustainable catalytic applications.