Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

Olefin Metathesis Polymerization: Acyclic Diene Metathesis (ADMET)00:53

Olefin Metathesis Polymerization: Acyclic Diene Metathesis (ADMET)

2.2K
Acyclic diene metathesis polymerization or ADMET polymerization involves cross-metathesis of terminal dienes, such as 1,8-nonadiene, to give linear unsaturated polymer and ethylene. As ADMET is a reversible process, the formed ethylene gas must be removed from the reaction mixture to complete the polymerization process.
Similar to cross-metathesis, ADMET also involves the formation of metallacyclobutane intermediate by [2+2] cycloaddition of one of the double bonds of a terminal diene with...
2.2K

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

A Minimally Invasive, Suturable Platform for Brain Monitoring.

medRxiv : the preprint server for health sciences·2026
Same author

Selective Molecular Ion-Gating at Electrochemical Interfaces for Accelerated Lithium Extraction.

Journal of the American Chemical Society·2026
Same author

Nanopipette confined hydrogel-catalyst networks for spatiotemporal monitoring of nanoplastics-induced oxidative stress in single cells.

Biosensors & bioelectronics·2026
Same author

Multi-indicator water-quality prediction in mining areas using a feature-tokenizer transformer with spatiotemporal features.

Environmental research·2026
Same author

The elusive <i>endo</i>-product of the archetypal Diels-Alder reaction of furan and maleic anhydride - observed in the solid state at last.

Chemical science·2026
Same author

Artificial Intelligence for Assessment and Feedback in Medical Education: Bibliometric Mapping Study and Thematic Evidence Map.

JMIR medical education·2026

Related Experiment Video

Updated: Jan 12, 2026

Improved Polydimethylsiloxane (PDMS) Double Casting via Silicone Oil Treatment for Densely Packed Microstructure Replication
07:01

Improved Polydimethylsiloxane (PDMS) Double Casting via Silicone Oil Treatment for Densely Packed Microstructure Replication

Published on: July 18, 2025

1.4K

Transparent and Recyclable PDMS Adhesive Enabled by Dynamic Diels-Alder Cross-linking.

Zackery E Moreau1, Ayush Tiwary1, Rachel Blau1

  • 1Aiiso Yufeng Li Family Department of Chemical and Nano Engineering, University of California San Diego, 9500 Gilman Drive, Mail Code 0448, La Jolla, California 92093-0448, United States.

ACS Macro Letters
|November 6, 2025
PubMed
Summary
This summary is machine-generated.

This study introduces ReCLIP, a novel polymer adhesive using reversible Diels-Alder chemistry for easier electronic device recycling. This thermally responsive material enables controlled debonding, reducing destructive processing and enhancing component recovery.

More Related Videos

Fabrication of Large-area Free-standing Ultrathin Polymer Films
10:08

Fabrication of Large-area Free-standing Ultrathin Polymer Films

Published on: June 3, 2015

15.9K
Microfabricated Platforms for Mechanically Dynamic Cell Culture
15:21

Microfabricated Platforms for Mechanically Dynamic Cell Culture

Published on: December 26, 2010

14.1K

Related Experiment Videos

Last Updated: Jan 12, 2026

Improved Polydimethylsiloxane (PDMS) Double Casting via Silicone Oil Treatment for Densely Packed Microstructure Replication
07:01

Improved Polydimethylsiloxane (PDMS) Double Casting via Silicone Oil Treatment for Densely Packed Microstructure Replication

Published on: July 18, 2025

1.4K
Fabrication of Large-area Free-standing Ultrathin Polymer Films
10:08

Fabrication of Large-area Free-standing Ultrathin Polymer Films

Published on: June 3, 2015

15.9K
Microfabricated Platforms for Mechanically Dynamic Cell Culture
15:21

Microfabricated Platforms for Mechanically Dynamic Cell Culture

Published on: December 26, 2010

14.1K

Area of Science:

  • Materials Science
  • Polymer Chemistry
  • Sustainable Engineering

Background:

  • Consumer device design often overlooks recyclability, leading to destructive processing of components.
  • Current recycling methods for electronics involve incineration or mechanical methods, damaging valuable materials.
  • Reversible adhesives offer a potential solution for controlled debonding and improved recyclability.

Purpose of the Study:

  • To develop a reversibly cross-linked interlayer polymer (ReCLIP) for controlled debonding in consumer devices.
  • To investigate the influence of Diels-Alder adduct diastereomers on polymer network properties.
  • To characterize the thermal curing and debonding behavior of the ReCLIP system.

Main Methods:

  • Synthesis of furan-functionalized silicone chains and aromatic bismaleimide.
  • Curing via thermally reversible Diels-Alder reaction.
  • Characterization using 2D 1H-1H COSY NMR and 1D 1H NMR spectroscopy.
  • Evaluation of thermal stability, adhesion strength (lap-shear), and transparency.

Main Results:

  • The exo-endo ratio of the Diels-Alder adduct significantly impacted thermal stability and adhesion.
  • Diels-Alder cross-linking was rapid at 80 °C and achieved high conversion at 60 °C.
  • The retro-Diels-Alder reaction initiated around 90 °C.
  • ReCLIP demonstrated a shear strength of 286 ± 50 kPa, comparable to silicone adhesives, with excellent transparency and stability.

Conclusions:

  • ReCLIP, based on thermally reversible Diels-Alder chemistry, provides a viable route for creating recyclable electronic devices.
  • The tunable nature of the Diels-Alder reaction allows for control over adhesion and debonding temperatures.
  • This reversible adhesive technology can reduce waste and facilitate the recovery of high-value components from electronic waste.