Fe-Ce Bimetallic MOFs for Water Environment Remediation: Efficient Removal of Fluoride and Phosphate

Fe-Ce-MOFs with a rice-grain-like morphology were successfully obtained via hydrothermal synthesis, where ferric chloride (FeCl₃) and cerium nitrate [Ce(NO₃)₃] served as the metal precursors and terephthalic acid (PTA) acted as the organic coordinating ligand. The effects of the Fe:Ce molar ratio, (Fe/Ce):PTA ratio, reaction duration, and synthesis temperature on adsorption performance of the Fe-Ce-MOFs were systematically studied. A comprehensive evaluation was conducted on the removal of fluoride and phosphate ions from aqueous solution. Under optimized conditions, the maximum adsorption capacities of Fe-Ce-MOFs for fluoride and phosphate reached 183.82 mg g^-1 and 110.74 mg g^-1, respectively. Adsorption data correlated strongly with the Langmuir isotherm, were best represented by the pseudo-second-order kinetic model, and were identified as a spontaneous and endothermic reaction. After three regeneration cycles, the adsorbent still maintained high removal efficiencies for fluoride (85.17%) and phosphate (47.34%) removal. In practical wastewater treatment, removal efficiencies of 92.04% for fluoride and 93.87% for phosphate were achieved. Mechanistic studies revealed that fluoride removal was dominated by electrostatic attraction and hydroxyl-fluoride ion exchange, whereas phosphate removal was attributed to the generation of inner-sphere complexes involving PO₄^3- and Fe/Ce active sites. This study not only elucidates the synergistic mechanism of fluoride and phosphate elimination by Fe-Ce-MOFs but also provides theoretical guidance and application prospects for the development of highly efficient and stable bimetallic MOF-based adsorbents for environmental remediation.