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Updated: Jan 11, 2026

The Preparation and Properties of Thermo-reversibly Cross-linked Rubber Via Diels-Alder Chemistry
Published on: August 25, 2016
Industrial Vegetable Oils: A Green Alternative for Enhancing Rubber Properties
Julijana Žeravica1, Olga Govedarica1, Mirjana Jovičić1
1Faculty of Technology Novi Sad, University of Novi Sad, 21000 Novi Sad, Serbia.
Industrial hempseed oil shows promise as a sustainable rubber compounding alternative. This eco-friendly extender oil reduces rubber hardness and mixing energy, offering a greener solution to petroleum-based oils.
Area of Science:
- Materials Science
- Sustainable Chemistry
- Polymer Engineering
Background:
- Growing regulatory pressure on polycyclic aromatic hydrocarbons (PAH) necessitates alternatives to petroleum-based extender oils in rubber compounding.
- Industrial hempseed oil presents a potential sustainable and eco-friendly option for rubber formulations.
- Evaluating vegetable oils alongside petroleum-based oils is crucial for identifying viable replacements.
Purpose of the Study:
- To investigate the viability of industrial hempseed oil as a sustainable extender oil in rubber compounding.
- To analyze the physical and mechanical properties of rubber composites incorporating industrial hempseed oil.
- To compare the performance of industrial hempseed oil with various vegetable and petroleum-based oils.
Main Methods:
- Utilized automated neural networks for analyzing rubber composite properties.
- Compared rubber compounds with varying concentrations (0-30 phr) of industrial hempseed oil, six vegetable oils, and three petroleum-based oils.
- Performed sensitivity analysis to identify key factors influencing rubber hardness.
Main Results:
- Compounds with 20 phr of industrial hempseed oil and raw soybean oil achieved the highest cure rate index (64.32 1/min).
- Industrial hempseed oil reduced rubber hardness by 18% compared to conventional oils, reaching 40.5 Shore A at 30 phr.
- Mixing energy consumption decreased by up to 12% for vegetable oil samples versus mineral oils.
- Neural network predictions for cure rate index, hardness, and power consumption exceeded 99.2% validation performance.
Conclusions:
- Industrial hempseed oil is a viable and effective eco-friendly substitute for conventional mineral oils in rubber compounding.
- The use of industrial hempseed oil contributes to enhanced processing efficiency and reduced energy consumption.
- This research supports the adoption of sustainable materials in the rubber industry, aligning with environmental regulations.
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