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Updated: Jan 11, 2026

Spectrophotometric Determination of Phycobiliprotein Content in Cyanobacterium Synechocystis
Published on: September 11, 2018
Visible absorption spectra of mass-selected cyanobenzene and iso-cyanobenzene cations in solid neon
Shu-Yu Lin1, Sheng-Lung Chou2, Wen-Jian Huang2
1Department of Applied Chemistry and Institute of Molecular Science, National Yang Ming Chiao Tung University, Hsinchu 300093, Taiwan. cmtsengjimmy@nycu.edu.tw.
Abstract:
We report the visible absorption spectra of mass-selected cyano-benzene (C6H5CN+) and iso-cyano benzene (C6H5NC+) cations isolated in solid neon at 3 K using the mass-selected matrix isolation spectroscopy technique. The strong absorptions observed between 500 and 580 nm are assigned to the overlapping B 2B2 ← X 2B1 and C 2B1 ← X 2B1 transitions of C6H5CN+, which are in good agreement with recent gas-phase He-tagging measurements and Franck-Condon simulations. The additional weak features are attributed to C6H5NC+, supported by the detection of a distinct NC stretching vibration at 2043.3 cm-1 in the IR spectrum and corroborated by quantum chemical calculations. Analysis of the integrated IR intensities suggests that the iso-cyanobenzene cation comprises only ∼7-5% of the cyano-benzene cation population under our deposition conditions. The present work provides the first condensed-phase benchmark spectra of cyano-substituted benzene cations, expanding the spectroscopic database of aromatic cations under cryogenic conditions.
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