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Printability Metrics and Strain Rate Sensitivity of Multirole PVDF in Extrusion-Based Additive Manufacturing.

Nectarios Vidakis1, Nektarios K Nasikas2, Nikolaos Michailidis3,4

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Summary

This study explores how strain rate affects 3D printed Polyvinylidene fluoride (PVDF) components. Higher loading speeds enhance PVDF

Keywords:
Thermal evaluationelongation speedpolyvinylidene fluoride (PVDF)rheological evaluationstrain ratethree-dimensional (3D) printing

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Area of Science:

  • Materials Science
  • Additive Manufacturing
  • Polymer Engineering

Background:

  • Additive Manufacturing (AM) utilizes multirole materials, with Polyvinylidene fluoride (PVDF) being a prime candidate due to its unique properties.
  • Understanding the relationship between macroscopic mechanical behavior and microscopic structural mechanisms is crucial for optimizing AM components.

Purpose of the Study:

  • To establish a correlation between macroscopic mechanical behavior and microscopic structural mechanisms in AM PVDF.
  • To investigate the influence of deformation rate on the mechanical response of 3D printed PVDF components.
  • To evaluate the performance of AM PVDF under various strain rates relevant to real-life applications.

Main Methods:

  • Testing of AM PVDF samples across a range of strain rates (10-300 mm/min).
  • Characterization using thermogravimetric analysis, differential scanning calorimetry, rheological measurements, scanning electron microscopy, dynamic mechanical analysis, Raman spectroscopy, and energy-dispersive spectroscopy.
  • Evaluation of mechanical properties including ultimate and yield strengths, modulus of elasticity, toughness, flexural strength, Charpy impact strength, and Vickers hardness.

Main Results:

  • PVDF demonstrated a strain-hardening response, with strength increasing up to ~25% and stiffness by ~15% as loading speed increased.
  • AM PVDF samples exhibited resilience under extreme strain rate conditions.
  • Sensitivity index data provided insights into material response variations.

Conclusions:

  • The deformation rate can be effectively utilized to tailor the mechanical response of 3D printed PVDF components.
  • AM PVDF shows promising mechanical characteristics and resilience, making it suitable for demanding applications.
  • The study provides a comprehensive understanding of PVDF behavior under dynamic loading.