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Published on: March 2, 2021
A vinylene-linked porphyrin covalent organic framework for efficient sunlight-driven photocatalytic organic
Xiao-Meng Zhang1,2,3, Jing-Lan Kan3, Ying Dong3
1State Key Laboratory of Fine Chemicals, Frontier Science Center for Smart Materials, School of Chemical Engineering, Dalian University of Technology, Dalian, 116024, China. liuch1115@dlut.edu.cn.
Abstract:
A vinylene-linked porphyrin-based COF was synthesized via aldol condensation reaction. This COF demonstrates prominent exciton dissociation and charge transfer, exhibiting exceptional photoactivity in the photooxidation of sulfides and oxidative coupling of benzylamines under sunlight irradiation.
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