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Published on: August 2, 2019
Janus VAZ3H (A = Si, Ge; Z = N, P) single layers exhibiting valley polarization, magnetic anisotropy, and topological
Yang Yang1,2, Yanyang Cao1,2, Shao-Jie Zhang1,2
1School of Electronics and Information, Zhengzhou University of Light Industry, Zhengzhou, China. yyphysics@zzuli.edu.cn.
Abstract:
Using first-principles calculations, we explore the electronic and topological properties of Janus VAZ3H single layers (A = Si, Ge; Z = N, P) that are dynamically and thermally stable. In the strain-free state, VSiN3H, VSiP3H, and VGeN3H demonstrate direct bandgap ferrovalley (FV) semiconducting properties, while VGeP3H displays an indirect bandgap. The easy magnetization axis varies among these materials, with VSiN3H and VGeN3H preferring in-plane magnetization, whereas VSiP3H and VGeP3H favor out-of-plane magnetization. Furthermore, the electronic structure analysis reveals valley polarization at the K and K' points. When subjected to strain, these systems experience phase transitions, such as direct-to-indirect bandgap shift, the evolution from FV semiconducting to half-valley metal (HVM), and the emergence of a quantum anomalous Hall (QAH) phase within certain strain intervals. The QAH phase is identified by chiral edge states and quantized anomalous Hall conductivity (AHC), supported by an integer AHC plateau of 1e2/h and a Chern number of 1. These results highlight the tunability of VAZ3H SLs through strain engineering, providing a potential platform for valleytronic and topological applications.
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