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Mitigating Ion Migration with Alternating Voltage for Stable Perovskite Image Sensors.
Sergey Tsarev1,2, Yuliia Kominko1,2, Kyuik Cho3
1Laboratory of Inorganic Chemistry, Department of Chemistry and Applied Biosciences, ETH Zürich, Zürich CH-8093, Switzerland.
ACS Applied Materials & Interfaces
|December 10, 2025
Summary
Perovskite photodetectors offer high sensitivity for cameras. A novel forward voltage pulse method stabilizes their performance by mitigating ion migration, enabling over 180 hours of operation.
Area of Science:
- Materials Science
- Electronics Engineering
- Optoelectronics
Background:
- Perovskite photodetectors are promising alternatives to silicon photodiodes for camera applications due to their high sensitivity and integration capabilities.
- Conventional CMOS image sensor integration requires reverse bias, which causes performance instability in perovskite photodetectors due to ion migration.
Purpose of the Study:
- To develop a method to stabilize perovskite photodetector performance in CMOS image sensors.
- To overcome the ion migration issue that limits the operational stability of perovskite photodetectors.
Main Methods:
- Applying forward voltage pulses after each signal integration cycle to counteract ion migration.
- Operating perovskite photodetectors under alternating voltage pulses.
- Fabricating and testing 8x8 crossbar arrays of perovskite photodetectors.
Main Results:
- The proposed forward voltage pulse technique enabled stable operation of perovskite photodetectors for over 180 hours.
- Constant reverse bias resulted in detector degradation within 10 minutes.
- Stable imaging was demonstrated using the developed perovskite photodetector arrays.
Conclusions:
- Forward voltage pulsing is an effective strategy to stabilize perovskite photodetectors against ion migration.
- This technique significantly enhances the operational lifetime and reliability of perovskite photodetectors for imaging applications.
- Perovskite photodetectors are viable for stable, high-performance imaging sensors.

