Microwave-Crosslinked Polymer Binder MA-AANa/D Biodegradable in an Aqueous Environment-Selected Own Research.
Beata Grabowska1, Artur Bobrowski1, Mateusz Skrzyński1
1Faculty of Foundry Engineering, Department of Foundry Process Engineering, AGH University of Krakow, al. A. Mickiewicza 30, 30-059 Krakow, Poland.
Materials (Basel, Switzerland)
|December 11, 2025
Summary
This study introduces a reusable polymer binder (MA-AANa/D) for casting. Microwave treatment enables binder regeneration and confirms its biodegradability, meeting industry standards.
Area of Science:
- Materials Science
- Polymer Chemistry
- Environmental Science
Background:
- Traditional polymer binders pose environmental challenges.
- Developing sustainable and reusable binders is crucial for the casting industry.
Purpose of the Study:
- To evaluate the reusability and biodegradability of a novel polymer binder, MA-AANa/D.
- To confirm the binder's suitability for casting applications and its environmental safety.
Main Methods:
- Fourier-transform infrared (FT-IR) spectroscopy to analyze microwave-induced crosslinking.
- Bending strength (Rgu) tests to assess binder performance in casting sand.
- Zahn-Wellens test and chemical oxygen demand (UV-Vis) measurements to evaluate biodegradability.
Main Results:
- Microwave radiation effectively crosslinks the MA-AANa/D binder and moulding sand.
- The binder's properties are restored upon simple treatment, demonstrating reusability.
- Achieved bending strength meets requirements for mould and core production.
- MA-AANa/D exhibited significant biodegradability (63.5% Rt after 28 days).
Conclusions:
- The MA-AANa/D polymer binder is reusable in casting processes after microwave-assisted regeneration.
- The binder demonstrates excellent biodegradability, making it an environmentally friendly option.
- This novel binder offers a sustainable solution for the foundry industry.


