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Updated: May 13, 2026

A Simple, Low-cost, and Robust System to Measure the Volume of Hydrogen Evolved by Chemical Reactions with Aqueous Solutions
Published on: August 17, 2016
Hydrostatic Water Displacement Sensing for Continuous Biogas Monitoring
Marek Habara1, Jozef Molitoris1, Barbora Jankovičová2
1Faculty of Mechanical Engineering, Slovak University of Technology in Bratislava, Námestie Slobody 17, 812 31 Bratislava, Slovakia.
Abstract:
Biogas and biomethane represent promising domestic fuels compatible with decarbonization targets at a time when diversification of gas sources is essential due to market volatility and increasing security risks. In laboratory practice, however, biogas production is still frequently assessed manually, which increases measurement uncertainty, limits temporal resolution, and reduces comparability between experimental series. We present an open and low-cost platform for continuous monitoring based on the hydrostatic water-displacement principle, complemented by stabilized process conditions (temperature control at 37 °C with short-term variability of approximately ±0.02 °C), continuous measurement with a 1 Hz sampling rate, and cloud-based data visualization. The methodology builds on a standardized procedure grounded in well-defined pressure-height-volume conversion relationships and transparent signal processing, enabling objective comparison of substrates and experimental setups. Validation experiments confirmed the system's capability to capture short-term transient phenomena, improve reproducibility among parallel reactors, and maintain long-term measurement stability. Long-duration tests demonstrated short-term scatter of approximately 0.06 mL, minimal drift below 0.15% per 24 h, and an expanded uncertainty of roughly 3.1% at 100 mL. In parallel BMP tests, the continuous method yielded final volumes 5.78% higher than the discrete pressure method, reflecting systematic bias introduced by sparse manual sampling and reactor handling. The basic configuration quantifies the cumulative volume and production rate of biogas and is readily extendable to online gas composition analysis. The proposed solution offers a replicable tool for research and education, reduces costs, supports measurement standardization, and accelerates the optimization and subsequent scale-up of biogas technologies toward pilot-scale and industrial applications.

