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Published on: July 17, 2020
Cyclopropenes in Photochemical Reactions
David Suárez-García1, Darío Coto1, Rubén Vicente1
1Departamento De Química Orgánica e Inorgánica, Instituto Universitario de Química Organometálica "Enrique Moles" and Centro de Innovación en Química Avanzada (ORFEO-CINQA), Universidad De Oviedo, Oviedo, Spain.
None:
This review covers the reactivity of cyclopropenes under light irradiation. Cyclopropenes have a formidable and complex photochemistry. While fundamental photochemistry of cyclopropenes was early studied, the synthetic potential has not been developed at comparable pace as synthetic photochemistry has recently evolved. In this review, the main types of light-mediated reactivity of cyclopropenes is briefly presented and focus on the synthetic possibilities offered by these reactions. Moreover, photochemical reactions in which cyclopropenes at ground state react with other photo-excited molecules are also presented. Finally, the value of cyclopropenes in a different field as light-mediated bio-orthogonal reactions is succinctly introduced.
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