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Updated: Jan 8, 2026

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Published on: June 13, 2020
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Salinity-driven stratification enhances riverine mercury export to the coastal ocean
Roland P Ovbiebo1, Cathryn D Sephus1, Amina T Schartup1
1Scripps Institution of Oceanography, University of California San Diego, USA.
Summary
Estuarine stratification significantly increases mercury (Hg) export to coastal oceans, with potential for greater methylmercury (MeHg) production. Climate change may intensify this effect, impacting ocean Hg levels.
Area of Science:
- Environmental Chemistry
- Oceanography
- Ecosystem Dynamics
Background:
- Rivers are major pathways for mercury (Hg) transport to coastal oceans, with estuaries playing a critical role.
- Estuarine circulation and stratification significantly influence the export of metals, including Hg, but their specific impact on Hg transformation and methylation is not fully understood.
Purpose of the Study:
- To investigate the influence of estuarine stratification on mercury (Hg) transport and methylmercury (MeHg) production.
- To model Hg transformation under varying salinity-driven stratification regimes (well-mixed, slightly stratified, highly stratified).
Main Methods:
- Development of three numerical models to simulate Hg transformation.
- Utilized data from the Chesapeake Bay (CPB) and Hudson River Estuary (HRE) in the U.S.A.
- Assessed Hg export and burial under different stratification scenarios.
Main Results:
- Stratification increases riverine Hg export by 19% in CPB and 20% in HRE.
- Shorter Hg residence times under stratification promote faster export, while unstratified conditions favor Hg burial.
- Slightly stratified conditions in CPB led to an 11.5% increase in MeHg production and a 16.4% increase in MeHg export.
Conclusions:
- Estuarine stratification enhances Hg and MeHg export to coastal oceans.
- Seasonal river discharge variations influence stratification and Hg export dynamics.
- Projected increases in estuarine stratification due to climate change may lead to elevated Hg and MeHg inputs into coastal marine environments.
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