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Updated: Jan 8, 2026

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Published on: February 7, 2022
Reversible Photoswitching of Donor-Acceptor Stenhouse Adducts in Water
Francisco G Blandón-Cumbreras1, Marek Jurtík2, Aneta Závodná2
1CIQSO - Center for Research in Sustainable Chemistry and Department of Chemistry, University of Huelva, Campus de El Carmen s/n, E-21071 Huelva, Spain.
Abstract:
Adamantane-substituted donor-acceptor Stenhouse adducts (DASA) form highly stable host-guest complexes with cucurbit[n]urils (n = 7, 8) in water. These assemblies show kinetic stabilization of the colored linear form and, remarkably, exhibit reversible T-type photoswitching in water. These so far elusive features for first-generation DASA reveal a strategy for their potential use in biorelevant contexts.
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