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Updated: Jan 8, 2026

Effect of Bending on the Electrical Characteristics of Flexible Organic Single Crystal-based Field-effect Transistors
Published on: November 7, 2016
Flexible n-Channel Organic Transistors with Low Contact Resistance
Sabrina Steffens1, Tobias Wollandt1, Karla Cordero-Solano1
1Max Planck Institute for Solid State Research, Heisenbergstraße 1, Stuttgart 70569, Germany.
Researchers developed n-channel organic thin-film transistors (TFTs) using novel semiconductors. Functionalized contacts with 4-(methylsulfanyl)-thiophenol achieved record-low contact resistance on silicon and flexible substrates, demonstrating excellent bending stability.
Area of Science:
- Organic electronics
- Materials science
- Semiconductor physics
Background:
- Advancements in organic semiconductors are crucial for developing flexible and low-cost electronic devices.
- Improving charge injection and transport in n-channel organic thin-film transistors (TFTs) remains a key challenge.
- Contact resistance significantly impacts the performance of organic TFTs.
Purpose of the Study:
- To fabricate and characterize n-channel organic TFTs using three promising small-molecule organic semiconductors.
- To investigate the effect of contact functionalization on device performance, particularly contact resistance.
- To evaluate device performance on both rigid silicon and flexible polymeric substrates.
Main Methods:
- Fabrication of inverted staggered and inverted coplanar n-channel TFTs using TAPP-Br4, ActivInk N1100, and PhC2-BQQDI.
- Functionalization of source and drain contacts with four different thiols, including 4-(methylsulfanyl)-thiophenol (MeSTP).
- Electrical characterization of TFTs on silicon and flexible substrates under ambient conditions.
Main Results:
- PhC2-BQQDI based TFTs with MeSTP-functionalized contacts exhibited the best performance.
- Record-low contact resistances of 130 Ω cm (silicon) and 210 Ω cm (flexible substrates) were achieved.
- TFTs on flexible substrates demonstrated excellent bending stability and performance in ambient air.
Conclusions:
- Contact functionalization with MeSTP effectively minimizes contact resistance in n-channel organic TFTs due to its low effective work function.
- The developed organic TFTs show potential for high-performance, flexible electronic applications.
- Achieving low contact resistance in ambient air is a significant step towards practical organic electronics.
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