Chemistry in a Cryogenic Buffer Gas Cell

Cryogenic buffer gas sources are ubiquitous for producing cold, collimated molecular beams for quantum science, chemistry, and precision measurements. The molecules are typically produced by laser ablating a metal target in the presence of a donor gas. The radical of interest emerges due to a barrier-free reaction or under thermal or optical excitation. High-barrier reactions, such as between Ca and H₂, should be precluded. We study chemical reactions between Ca and three hydrogen isotopologues (H₂, D₂, and HD) in a cryogenic cell with helium buffer gas. We observe that H₂ can serve as both a reactant and a buffer gas, outperforming D₂ and HD. We use a reaction network model to describe the chemical dynamics and find that the enhanced molecular yield can be attributed to rapid vibrational excitations of the reactant gas. Our results demonstrate a robust method for generating bright cold beams of alkaline-earth-metal hydrides for laser cooling and trapping.