Molecular Diode-Based Covalent Organic Frameworks: Imine Orientation-Driven Acid-Base Switching Photocatalytic H2

Tianyi Liu1, Yunjie Lang1, Ning Sun1

  • 1Institute of Frontier Chemistry, School of Chemistry and Chemical Engineering, Shandong University, Qingdao, Shandong, China.

Summary

Researchers developed new donor-acceptor covalent organic frameworks (D-A COFs) that act like molecular diodes. These materials show switchable photocatalytic activity for hydrogen evolution, controlled by pH-responsive electron transfer.

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