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Updated: Jan 7, 2026
Electrophoretic Crystallization of Ultrathin High-performance Metal-organic Framework Membranes
Published on: August 16, 2018
One-step synthesis of porous ionic liquids via proton transfer for natural gas purification
Huiqin Xu1, Zixuan Xu1, Qing Zhao1
1State Key Laboratory of Coordination Chemistry, Jiangsu Key Laboratory of Clean Energy Catalysis and Intelligent Green Chemical Engineering, Suzhou Key Laboratory of Green Intelligent Manufacturing of New Energy Materials and Devices, Institute of Green Chemistry and Engineering, School of Chemistry and Chemical Engineering, Nanjing University, Jiangsu 215163, P.R. China. xmzhang@nju.edu.cn.
Abstract:
The proton transfer strategy was applied to prepare porous liquids (PLs) via one-step mixing at room temperature. Benefiting from the dual effects of the cavities of UiO-66-OH and the reversible addition reaction between carbonyl sites and H2S, the selective capture of H2S over CO2 and CH4 is achieved. Additionally, these PLs can catalyze the reaction of H2S with α,β-unsaturated carboxylic acid esters to generate thiols and thioethers.
