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Waterborne Glass Fiber Sizing Agents: Soft-Hard Janus Particles.

Tianlin Liu1, Hailing He2, Fuxin Liang1

  • 1Department of Chemical Engineering, Tsinghua University, Beijing 100084, China.

ACS Applied Materials & Interfaces
|January 9, 2026
PubMed
Summary
This summary is machine-generated.

Soft-hard Janus particles (JPs) enhance glass fiber (GF) reinforced polypropylene (PP) composites. This interface modification improves mechanical properties by increasing surface roughness and creating a gradient modulus interphase layer.

Keywords:
Janus particlecompositeglass fiberinterface modificationsizing agent

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Area of Science:

  • Materials Science
  • Polymer Science
  • Composite Materials

Background:

  • Interface modification is key to enhancing mechanical properties in glass fiber (GF) reinforced polypropylene (PP) composites.
  • Sizing agents play a crucial role in optimizing the interface between fibers and the polymer matrix.

Purpose of the Study:

  • To design and synthesize soft-hard Janus particles (JPs) for GF sizing agents.
  • To investigate the effects of JPs on the interfacial properties and mechanical performance of GF/PP composites.

Main Methods:

  • Janus particles (JPs) synthesized via polymerization-induced phase separation of seeded emulsion.
  • JPs incorporated into a waterborne GF sizing agent for interface modification.
  • Characterization of surface properties (roughness, surface energy) and interfacial layer (modulus, thickness).

Main Results:

  • JPs increased GF surface roughness (Ra) from 6.3 to 23.1 nm.
  • JPs reduced polar surface energy from 30.20 to 25.48 mJ/m².
  • A gradient modulus interphase layer (~244 nm) formed, dissipating fracture energy via microdeformation.

Conclusions:

  • JPs synergistically enhance interfacial adhesion, nanoscale roughness, and create a gradient modulus interphase.
  • This modification simultaneously strengthens and toughens GF/PP composites.
  • JPs show promise for advanced composite interfacial engineering.