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Constraint driven modulation of N,N-diarylamine(s) under space limitations imprinted in 7.6.6 defect

Krzysztof Dzieszkowski1, Krzysztof Kruczała1, Monika Kijewska2

  • 1Faculty of Chemistry, Jagiellonian University, Gronostajowa 2, 30-387 Kraków, Poland. pawlicki@chemia.uj.edu.pl.

Chemical Communications (Cambridge, England)
|January 12, 2026
PubMed
Summary

Sterically crowded N,N-diarylamine systems undergo spontaneous transformation via neutral radicals. This step-by-step oxidation process leads to novel, fully conjugated diatropic systems with modified properties.

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