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Constraint driven modulation of N,N-diarylamine(s) under space limitations imprinted in 7.6.6 defect
Krzysztof Dzieszkowski1, Krzysztof Kruczała1, Monika Kijewska2
1Faculty of Chemistry, Jagiellonian University, Gronostajowa 2, 30-387 Kraków, Poland. pawlicki@chemia.uj.edu.pl.
Abstract:
The behaviour within any constraint-based chemical system is strictly correlated with the potential strain-release that drives possible transformation(s) leading to the properties modification. An involvement of N,N-diarylamine into a sterically crowded system incorporating three dynamic and potentially removable hydrogens defines an unprecedented and spontaneous transformation that follows a step-by-step oxidation process via a neutral radical to form a fully conjugated diatropic system.
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