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Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides
Published on: May 26, 2019
Quaternary aminostratigraphies for the eastern North European Plain
Ellie Nelson1, Dustin White1, Lucy Wheeler1
1Department of Chemistry, University of York Department of Chemistry, York, England, YO10 5DD, UK.
This study introduces new amino acid geochronology (AAG) aminostratigraphies for the eastern North European Plain, aiding Quaternary climate change and archaeology research. These findings provide crucial relative dating for deposits spanning the last million years.
Area of Science:
- Quaternary geology
- Geochronology
- Archaeology
Background:
- The eastern North European Plain is vital for Quaternary climate and archaeological studies, but chronological dating of deposits is difficult.
- Amino acid geochronology (AAG), specifically intra-crystalline protein decomposition (IcPD) in *Bithynia* snail opercula, offers relative dating for Quaternary deposits.
- Previous IcPD studies focused on regions with assumed uniform diagenetic temperatures.
Purpose of the Study:
- To establish the first aminostratigraphies for the eastern North European Plain, covering deposits up to ~1 Ma.
- To assess existing age attributions of Middle and Late Pleistocene interglacials using these new aminostratigraphies.
- To investigate variations in IcPD extent due to diverse temperature histories across the region.
Main Methods:
- Development of aminostratigraphies using *Bithynia* opercula from the eastern North European Plain.
- Correlation of opercula data with regional pollen assemblages (Holsteinian, Eemian, Holocene).
- Evaluation of IcPD temporal resolution within interglacial periods.
Main Results:
- Presentation of four novel aminostratigraphies for the eastern North European Plain.
- Assessment of IcPD variations linked to regional temperature differences.
- Determination of IcPD's temporal resolution capabilities for interglacial dating.
Conclusions:
- The new aminostratigraphies serve as essential reference datasets for relative age estimation.
- This research enhances chronological control for the late Middle Pleistocene to Holocene in the study area.
- The findings improve understanding of Quaternary climate change and archaeological site dating in the eastern North European Plain.
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