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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
Published on: August 12, 2013
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Polymerization-induced fluoroacetonitrile-based heterogeneous lithium metal batteries
Zhixu Long1, Wei Xue1, Hongyang Shan1
1College of Aerospace Engineering, Chongqing University, Chongqing 400044, China. sfsong@cqu.edu.cn.
Abstract:
We report a polymerization-induced heterogeneous configuration (PIHC) that spatially confines a crosslinked fluoroacetonitrile (FAN)-based electrolyte at the cathode and a conventional ether electrolyte at the anode, effectively suppressing detrimental shuttling. The electrolyte retains ultrahigh ionic conductivities of 29.6 mS cm-1 at 25 °C and 4.44 mS cm-1 at -70 °C.
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