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Updated: Jan 27, 2026

Reverse Microemulsion-mediated Synthesis of Monometallic and Bimetallic Early Transition Metal Carbide and Nitride Nanoparticles
Published on: November 27, 2015
Hydro/Fluoro-phosphoro(di)thiolation of Allenamides: Toward SN2-Selective Transition-Metal-Free Formal
Raju Teegala1,2, Purna C R Bhavnari1, Kadiyala Sagar2
1Department of Chemistry, GITAM Deemed to Be University, Hyderabad, Telangana 502329, India.
Abstract:
Two versatile synthetic strategies for β-H/F-enamide-tagged phosphoro(di)thioates from allenamides are disclosed, relying on electrophilic activation via β-H and F-iminium species. These developed straightforward protocols demonstrate broad applicability in complex molecular contexts with remarkable chemo- and regioselectivity. The synthesized allylphosphorothioates (APTs) act as potent electrophiles, enabling SN2-selective allylic substitution with (hard)C-nucleophiles of all hybridizations to deliver hydrocarbonation products in seamless complement to transition-metal-driven strategies.
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