Related Experiment Video
Updated: Jan 28, 2026

Supercritical Nitrogen Processing for the Purification of Reactive Porous Materials
Published on: May 15, 2015
Multiscale simulation of salt crystallization-induced damage in porous materials
N Lo Presti1, A M D'Altri1, L Patruno1
1Department of Civil, Chemical, Environmental, and Materials Engineering (DICAM), University of Bologna, Viale del Risorgimento 2, 40136 Bologna, Italy.
None:
In this paper, a multiscale modelling strategy to simulate salt crystallization-induced damage in porous materials is proposed. Salt crystallization pressure exerted on pore walls is explicitly modelled on a nonlinear representative volume element (RVE) at the microscale of the porous medium. A macroscopic damage measurement of the whole RVE can be then extracted for any combination of crystallization pressure and pore filling time histories. The efficient coupling of moisture transport and salt crystallization with micromechanical damage is achieved by adopting a state-of-the-art multiphase model for the transport/crystallization part and by originally formulating an efficient phenomenological damage model, trained on a dataset generated through micromechanics-based simulations on RVEs. The effectiveness of this numerical strategy is shown via the comparison with an experimental campaign on salt-aged traditional Dutch tiles. The proposed numerical strategy appeared able to track the evolution of macroscopic damage in real-time along with salt transport and crystallization within the porous medium. The potential for using the proposed framework with extended datasets and simulation-driven machine learning is also highlighted.
Related Concept Videos
Determining the pH of Salt Solutions
Responses to Salt Stress
Ionic Crystal Structures
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
Crystal Growth: Principles of Crystallization
Initiating crystallization involves manipulating the concentration of the solute and the temperature of the solution. Since crystal growth occurs when the ratio of concentration and solubility of the solute in the solvent...
Crystal Field Theory - Octahedral Complexes
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
Crystal Field Theory - Tetrahedral and Square Planar Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...

