Metasurfaces with Phase-Change Materials for Mid-Wave Infrared Thermal Management

Applying coatings that suppress the radiance changes related to temperature-dependent blackbody emission enables temperature-independent optical and sensing systems. Phase-change materials can significantly modify their optical properties within their transition window, but compensating for the large mid-wave infrared (MWIR, 3-5 µm) variation is demanding: blackbody radiance at 3 µm increases nearly 10-fold as the temperature rises from 30 °C to 80 °C. Vanadium dioxide VO₂, whose insulator-metal transition offers a sharp contrast and a low-loss insulating state, is attractive for applications in thermal management, but simple thin-film designs cannot provide full compensation. We demonstrate metasurface coatings that provide this compensation by constructing an array of metal-VO₂-metal antennas tuned to maintain constant thermal emission at a target wavelength over a temperature range of 30 °C to 80 °C. Antennas of several lateral sizes are combined, so their individual resonances collectively track the Planck change. This design provides both optical contrast and the correct temperature derivative, which are unattainable with homogeneous layers. Our approach results in a negligible apparent temperature change of the metasurface across the 30-80 °C range, effectively masking thermal signatures from MWIR detectors stemming from the low losses of VO₂.