Bio-Based Pectin-Calcium Film and Foam Adsorbents with Immobilized Fe-BTC MOF for Water Contaminant Removal

Metal-organic frameworks (MOFs) offer high porosity for water remediation but face challenges in handling as powders. We address these limitations by physically immobilizing Fe-BTC MOF within calcium-crosslinked low-methoxyl pectin matrices (PE-Ca-MOF). Solvent-cast films and freeze-dried foams were fabricated using water-based and polyvinylpyrrolidone (PVP)-assisted Fe-BTC dispersions, preserving MOF and pectin structures confirmed by FT-IR. PVP improved Fe-BTC dispersion and reduced particle size, enhancing distribution and plasticizing the matrix proved by DSC. Incorporation of water-dispersed Fe-BTC increased the equilibrium adsorption capacity but reduced the initial adsorption rate, while the PVP-assisted foam further enhanced uptake in comparative batch tests through its more open porous structure. At pH 7, PE-Ca-5%MOF films showed high adsorption capacities and removal efficiencies for paraquat (35.5 mg/g, 70.6%) and tetracycline (14.5 mg/g, 46.8%), while maintaining Zn²⁺ uptake compared to calcium-pectin films without MOF. Adsorption followed pseudo-first-order kinetics and Langmuir isotherms. Green regeneration with acetic acid enabled >80% capacity retention over five adsorption-desorption cycles. Foam architectures increased porosity and active-site accessibility (SEM), improving performance even at lower MOF loadings. Overall, controlling MOF dispersion and composite morphology enables efficient, reusable, and environmentally friendly bio-based adsorbents for water purification.