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Published on: November 11, 2013
Waterborne Poly(urethane-urea)s for Lithium-Ion/Lithium-Metal Batteries
Bushra Rashid1, Anjum Hanief Kohli1, In Woo Cheong1
1Department of Applied Chemistry, Graduate School of Chemical Engineering and Applied Chemistry, Kyungpook National University, 80 Daehak-ro, Buk-gu, Daegu 41566, Republic of Korea.
Waterborne polyurethanes (WPU) and poly(urethane-urea)s (WPUU) offer sustainable battery manufacturing. These materials enable advanced designs for lithium-ion and lithium metal batteries, balancing key performance properties.
Area of Science:
- Materials Science
- Electrochemistry
- Polymer Chemistry
Background:
- Waterborne polyurethane (WPU) and waterborne poly(urethane-urea) (WPUU) dispersions offer sustainable, water-based processing for rechargeable batteries.
- These polymers provide tunable adhesion and mechanical properties, suitable for various battery components beyond traditional binders and coatings.
Purpose of the Study:
- To review the fundamentals of WPU/WPUU chemistry, including building blocks, dispersion, morphology, and film formation.
- To analyze WPU/WPUU applications in batteries (electrode binders, separators, electrolytes) through a structure-processing-property lens.
- To identify key performance trade-offs and provide formulation guidelines for optimizing battery performance.
Main Methods:
- Literature review of WPU/WPUU fundamentals and battery applications.
- Analysis of structure-property relationships in WPU/WPUU materials for energy storage.
- Examination of formulation variables and their impact on performance.
Main Results:
- WPU/WPUU chemistries can be tailored for electrode binders, separator coatings, and polymer electrolytes in lithium-ion and lithium metal batteries.
- Key trade-offs exist between adhesion and electrolyte uptake, and ionic conductivity and mechanical strength.
- Formulation choices (segment selection, ionic design, molecular weight, crosslinking) significantly influence performance.
Conclusions:
- WPU/WPUU materials are versatile for advanced battery designs, requiring careful formulation to balance performance metrics.
- Future work should focus on stable interlayers, enhanced electrochemical properties, and specific design guidelines for lithium metal batteries (LMB).
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