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Published on: April 22, 2016
Direct CO2-to-CO conversion with H2O on an In2O3 photocatalyst enabled by atomically precise Pd sites
Fengyang Yu1, Cheng Chang1, Hanghang Kang1
1State Key Laboratory of Chemistry and Utilization of Carbon Based Energy Resources, College of Chemistry, Xinjiang University, Urumqi, 830046, Xinjiang, PR China. yufengyang@xju.edu.cn.
None:
Via a MOF-templated strategy, we fabricated Pd single-atom-anchored In2O3 nanotubes with lattice-confined Pd-O-In coordination. This structure narrows the bandgap and boosts charge separation. In situ XPS and DFT calculations confirm Pd as CO2 reduction sites and In as water oxidation sites, enabling highly selective CO2 reduction with a 10-fold higher CO yield than pristine In2O3.
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