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Updated: Feb 1, 2026

Fabrication of Spatially Confined Complex Oxides
Published on: July 1, 2013
Pyridine Into Pyrrole Transformation Induced Within the Confinement of the Macrocycle
Paulina Krzyszowska1, Agata Burska-Jabłońska1, Mateusz Oberski1
1Department of Chemistry, University of Wroclaw, Wroclaw, Poland.
None:
The pyridine contracted to form the pyrrole ring. This transformation belongs to a unique class of reactions with the fundamental characteristic of the cleavage of the aromatic structure. By investigating the unusual coordination chemistry of N-confused pyriporphyrin with silver and gold ions, we observed this process and obtained several complexes that exhibited remarkable reactivity. This includes the reversible cleavage of C-O bonds and the selective demetallation of the outer metal ion.
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