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Published on: October 18, 2017
Scalable AIE emitters for luminescent solar concentrators: the role of fluorination
Andrea Nitti1, Elisavet Tatsi2, Enrico Magnani1
1Department of Chemistry and INSTM Research Unit, University of Pavia, Via Taramelli 12, Pavia 27100, Italy. dario.pasini@unipv.it.
Abstract:
We report on a series of novel π-conjugated organic emitters based on cores possessing different degrees of fluorination flanked by two naphthothiophene units, obtained through a chemically sustainable synthetic approach. The luminophores exhibit aggregation-induced emission (AIE) behavior, good compatibility, homogeneous distribution, and excellent photostability in thin-film LSCs based on a PMMA matrix. It was found that by increasing the degree of fluorination in the core the overall efficiency is preserved, while the photostability, which is extremely important in the context of application in energy efficient buildings, is substantially enhanced.
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