Tough transparent glass ceramics for multi-mode programmable dynamic tunable persistent luminescence via phase
Yixi Wu1, Xinkuo Li1, Chao Ruan1
1State Key Laboratory of Extreme Photonics and Instrumentation, College of Optical Science and Engineering, and School of Materials Science and Engineering, Zhejiang University, Hangzhou, China.
Nature Communications
|February 6, 2026
Summary
Researchers developed new transparent glass ceramics with tunable persistent luminescence. This breakthrough enables multi-dimensional information storage and encryption by controlling light emission in a single solid material.
Area of Science:
- Materials Science
- Solid-State Chemistry
- Optoelectronics
Background:
- Achieving multi-mode programmable dynamic tunable persistent luminescence in a single solid is crucial for advanced applications like multi-dimensional information storage and encryption.
- A significant challenge lies in effectively coupling luminescent centers with differentiated defect states within the material.
Purpose of the Study:
- To develop transparent glass ceramics capable of photo/thermally dynamic tunable afterglow.
- To establish a method for controlling the precipitation of defective nanocrystals and engineer the distribution of activators for tunable luminescence.
Main Methods:
- Utilizing a lithium-ion doping-assisted phase separation principle to control nanocrystal precipitation (Zn 1.7 SiO 4 : Li) within a glass matrix.
- Constructing a biphasic microenvironment with differentiated defect states.
- Engineering the distribution of Mn 2+ activators in both the amorphous glass matrix and nanocrystals to manipulate persistent luminescence color.
Main Results:
- Successfully created transparent glass ceramics exhibiting photo/thermally dynamic tunable afterglow.
- Demonstrated control over persistent luminescence color by engineering activator distribution.
- Achieved excellent material hardness (up to 10 GPa) and high thermal stability, suitable for harsh environments.
Conclusions:
- Pioneered a novel strategy for modulating dynamic afterglow in a single solid material.
- The developed transparent composites offer a promising platform for multi-dimensional information storage and encryption.
- The findings inspire further research into advanced luminescent materials for data security and storage.
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