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Distrontium oxalate tetra-hydroxidocuprate(II).

Hibiki Kunisawa1, Jun-Ichi Yamaura2, Toshihiro Nomura1

  • 1Department of Physics, Shizuoka University, Shizuoka 422-8529, Japan.

Iucrdata
|February 9, 2026
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Summary

The crystal structure of distrontium oxalate tetra-hydroxidocuprate(II) was determined. This study reveals a novel 3D framework built from strontium polyhedra, copper hydroxide units, and oxalate groups.

Keywords:
crystal structureinorganicoxalate

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Area of Science:

  • Inorganic Chemistry
  • Crystallography
  • Materials Science

Background:

  • Understanding the structure of novel inorganic compounds is crucial for materials science.
  • Metal-oxalate complexes exhibit diverse structural motifs and potential applications.

Purpose of the Study:

  • To determine the crystal structure of distrontium oxalate tetra-hydroxidocuprate(II).
  • To elucidate the coordination environment and bonding within the novel compound.

Main Methods:

  • Single-crystal X-ray diffraction was employed to determine the crystal structure.
  • The crystal structure was solved in the triclinic space group P1.

Main Results:

  • The asymmetric unit contains Sr, Cu, hydroxide groups, and oxalate anions.
  • A 3D framework is formed by edge-sharing {SrO4(OH)4} polyhedra, {Cu(OH)4} units, and oxalate groups.
  • Weak hydrogen bonds were observed within the framework.

Conclusions:

  • The crystal structure of distrontium oxalate tetra-hydroxidocuprate(II) was successfully determined.
  • The compound features a unique 3D framework with specific coordination environments around Sr and Cu ions.