Related Experiment Video
Updated: Feb 11, 2026

Flash Infrared Annealing for Perovskite Solar Cell Processing
Published on: February 3, 2021
Crystallization Regulation for Air-Processed, Efficient, and Stable Perovskite Solar Cells via In Situ
Zhengzheng Yao1,2, Xueying Li1,2, Lei Ning1,2
1State Key Laboratory of Bio-based Fiber Materials, Zhejiang Sci-Tech University, Hangzhou 310018, China.
Abstract:
Employing additives to regulate the intermediate phase configuration and their formation pathway is imperative for mitigating moisture interference on perovskite crystallization and structural perfection. Herein, we propose an in situ polymerization-assisted intermediate-phase transition strategy via incorporation of polymerizable ionic liquid 1-vinyl-3-ethylimidazolium bromide (VEImBr), which effectively shields perovskite crystallization from moisture interference. Thermodynamic analysis confirms a dynamic intermediate phase evolution from PbI2 (lead iodide)-VEImBr-N, N-dimethylformamide to PbI2-VEImBr and PbI2-is-(VEImBr) adducts during thermal annealing. This engineering favors perovskite nucleation and crystal growth kinetics while offering additional thermodynamics for α-phase perovskites. Moreover, the is-(VEImBr) polymer adheres to perovskite grain boundaries via hydrogen bonding and coordination interactions, reducing the defect density and improving the film performance. Consequently, the is-(VEImBr)-modified perovskite solar cells fabricated under open-air conditions deliver the champion efficiency of 22.57%, with the encapsulated devices maintaining 80% of its initial efficiencies after 900 h under damp-heat accelerated aging test (85 °C and 85% relative humidity).
Related Concept Videos
Phase Transitions
Phase Transitions: Sublimation and Deposition
Phase Transitions: Melting and Freezing
Phase Transitions: Vaporization and Condensation
Energy Diagrams, Transition States, and Intermediates
Chromatin Structure Regulates pre-mRNA Processing
The chromatin structure, especially...

