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Related Experiment Video

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Homochiral Indium-Oxo Clusters With Multichromatic Circularly Polarized Luminescence.

Dandan Liu1,2, Jiali Chen1,3, Jiao Wu1

  • 1State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, P. R. China.

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|February 12, 2026
PubMed
Summary

Researchers developed new chiral indium-oxo clusters (cInOCs) that emit strong circularly polarized luminescence (CPL). These clusters enable color-tunable CPL by encapsulating dyes, showing great potential for optical devices.

Keywords:
chiral indium‐oxo‐clusterschirality transfercircularly polarized luminescencedye encapsulationself‐assembly

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Area of Science:

  • Materials Science
  • Chemistry
  • Optics

Background:

  • Developing chiral main-group metal-oxo clusters (MOCs) for high-performance circularly polarized luminescence (CPL) is challenging.
  • Existing chiral MOCs often rely on dye doping, limiting intrinsic properties.

Purpose of the Study:

  • To present a generalizable strategy for synthesizing intrinsically CPL-active chiral indium-oxo clusters (cInOCs).
  • To explore the self-assembly, CPL properties, and applications of these novel cInOCs.

Main Methods:

  • Synthesis of chiral indium-oxo clusters (cInOCs).
  • Investigation of self-assembly into supramolecular structures.
  • Characterization of CPL properties and dye encapsulation.
  • Fabrication of flexible films for device applications.

Main Results:

  • Successfully synthesized cInOCs exhibiting intense blue CPL (glum = 0.012-0.013).
  • Demonstrated in situ dye encapsulation yielding tunable CPL composites (cInOCs@Dyes) with amplified chirality transfer (max glum = 0.037).
  • Developed processable films from cInOCs and cInOCs@Dyes composites.

Conclusions:

  • Introduced the first intrinsically CPL-active main-group MOCs, rivaling or surpassing dye-doped systems.
  • Achieved color-tunable CPL with significantly enhanced luminescence and chirality amplification.
  • Highlighted the potential of these materials for practical optical and photonic devices.